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Selenium-Ligated Palladium(II) Complexes as Highly Active Catalysts for Carbon—Carbon Coupling Reactions: The Heck Reaction.

✍ Scribed by Qingwei Yao; Elizabeth P. Kinney; Chong Zheng


Publisher
John Wiley and Sons
Year
2004
Weight
27 KB
Volume
35
Category
Article
ISSN
0931-7597

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A variety of palladium on activated carbon catalysts differing in Pd dispersion, Pd distribution, Pd oxidation state, and water content were tested in Heck reactions of aryl bromides with olefins. The optimization of the catalyst (structure ± activity relationship) and reaction conditions (temperatu