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Selenium chelates. Preparation and X-ray structure determination of methyl(diethyldiselenocarbamato)(triphosphine)platinum(II), Pt(Se2CNEt2)(CH3)(PPh3)

✍ Scribed by H.-W. Chen; J.P. Fackler Jr.; A.F. Masters; W.-H. Pan


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
224 KB
Volume
35
Category
Article
ISSN
0020-1693

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The reactions of tetrakis(triphenylphosp
✍ Pawan K. Khanna; Christopher P. Morley; Michael B. Hursthouse; K. M. Abdul Malik πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 431 KB

Treatment of tetrakis(tripheny1phosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a I : I mixture of [PtCl,(PPh,)J and the new compound [Pt(Se,CH,) (PPh,)J, which