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Reactions of the haloalcohols HO(CH2)nCl (n = 2, 3) with platinum(II) - alkynyl and -alkyne complexes. X-ray crystal structure of trans-[Pt(Me) {C(OCH2CH2Cl) (CH2Ph)} (PPh3)2] [BF4]

✍ Scribed by Umberto Belluco; Roberta Bertani; Rino A. Michelin; Mirto Mozzon; Franco Benetollo; Gabriella Bombieri; Robert J. Angelici


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
722 KB
Volume
240
Category
Article
ISSN
0020-1693

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The reactions of tetrakis(triphenylphosp
✍ Pawan K. Khanna; Christopher P. Morley; Michael B. Hursthouse; K. M. Abdul Malik 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 431 KB

Treatment of tetrakis(tripheny1phosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a I : I mixture of [PtCl,(PPh,)J and the new compound [Pt(Se,CH,) (PPh,)J, which