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Selectivity in ring-opening metatheses

✍ Scribed by John A. Tallarico; Michele L. Randall; Marc L. Snapper

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 596 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)01032-6

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✦ Synopsis

The development of new olefin metathesis catalysts has allowed for the introduction of unique synthetic transformations. In this regard, ring-opening metathesis (ROM) offers a novel means of constructing diene-containing systems. The factors behind the chemo-, regio-and stereoselectivities of ROM are examined. The mechanistic models suggested are supported by stoichiometric studies of the unique ruthenium alkylidenes formed during the ROM of various cyclobutene-containing substrates.

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