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Selectivity in inter- and intra-molecular photocycloaddition of ethenes to benzenoid compounds

โœ Scribed by D M Amey; A Gilbert


Book ID
105636700
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1998
Tongue
English
Weight
564 KB
Volume
110
Category
Article
ISSN
0253-4134

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Hydrogen fluoride elimination after IR-multiphoton excitation with pulsed CO;! laser radiation has been studied quantitatively with fluences up to 20 J cm-2 for FCH2CH2CH2C&,, FCH2CH2CH2CH2F, FCDHCH2CH2CH3, and FCDHCH2CH2CHZF. Efficient isotope separation shows that the R-CHDF chromophore can be sel