Selective tosylation of adenosine 5′-monophosphate
✍ Scribed by Morio Ikehara; Seiichi Uesugi
- Book ID
- 104248669
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 171 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
During the course of our study on purine cyclonucleosides (i> we have found that adenosine 5'-monophosphate (AMP) and its 8-bromD derivative (BrAMP) were tosylated only at 2'-OH by the tosylation in alkaline solution. These tosylates gave rise to 8,2'-
📜 SIMILAR VOLUMES
Adenyl cyclase and 3',5'-AMP1 have been implicated in the hormonal control mechanism of several biochemical reactions (1) and therefore the measurement of 3',5'-AMP in biological material is of interest. In the method of assay used by Rall and Sutherland (2, 3) and later modified by Brown, Clarke, R
The selective sulfonylation of 1 ,Sanhydroalditolsr -3 having the gluco and xylo configurations has previously been investigated, and the effects of the aglycon on the relative reactivity of the hydroxyl groups have been reported. The selective tosylation of 1,5-anhydro-D-galactitol (1) is now descr