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Selective Synthesis of Allenes and Alkynes through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates

โœ Scribed by Ohmiya, Hirohisa; Yang, Mingyu; Yamauchi, Yoshihiro; Ohtsuka, Yuhki; Sawamura, Masaya


Book ID
126988390
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
350 KB
Volume
12
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Selective Synthesis
โœ Hirohisa Ohmiya; Mingyu Yang; Yoshihiro Yamauchi; Yuhki Ohtsuka; Masaya Sawamura ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 1 views

## Abstract The linker chain length in the ligand decides on the formation of the allenes or propargyl derivatives, with the former obtained predominantly with the shorter chain (dppe) and the latter being preferred using Ph~2~Pโ€(CH~2~)~6~โ€PPh~2~ as a ligand.