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ChemInform Abstract: Selective Synthesis of Allenes and Alkynes Through Ligand-Controlled, Palladium-Catalyzed Decarboxylative Hydrogenolysis of Propargylic Formates.

✍ Scribed by Hirohisa Ohmiya; Mingyu Yang; Yoshihiro Yamauchi; Yuhki Ohtsuka; Masaya Sawamura

Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The linker chain length in the ligand decides on the formation of the allenes or propargyl derivatives, with the former obtained predominantly with the shorter chain (dppe) and the latter being preferred using Ph~2~P‐(CH~2~)~6~‐PPh~2~ as a ligand.

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