The selective synthesis of terephthalic acid from benzoic acid with carbon tetrachloride, copper powder and aqueous alkali was achieved by the use of -cyclodextrin ( -CyD) as a catalyst at 60°C under nitrogen of atmospheric pressure, producing terephthalic acid in 74 mol% yield with 100% selectivi
Selective synthesis of 4,4′-biphenyldicarboxylic acid using cyclodextrin as catalyst
✍ Scribed by Hidefumi Hirai; Yukihide Shiraishi; Kazuhiro Saito
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 210 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
The selective carboxylation of 4-biphenylcarboxylic acid with carbon tetrachloride in aqueous alkali to obtain 4,4'-biphenyldicarboxylic acid was achieved by the use of P-cyclodextrin and copper powder I1 under mild conditions.
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## Abstract For Abstract see ChemInform Abstract in Full Text.