๐”– Bobbio Scriptorium
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Selective reagents in chemical ionization mass spectrometry: Tetramethylsilane with aliphatic alcohols

โœ Scribed by Ron Orlando; Fred Strobel; D. P. Ridge; Burnaby Munson

Book ID
102965687
Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
772 KB
Volume
22
Category
Article
ISSN
1076-5174

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Cbemical ionization mpss spectra of halomethanes measured using tetramethylsiiaw as reagent gas exhibit three major peaks corresponding to [ M + SiMe,l\*, IM -XI + and (MeSi)lX+ ions (X = C1, Br or I). Dihalomethaws CH,X, form tbe most stable silylated molecular iom, whereas in the mass spectra of t

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Chemical ionization mass spectra of halogenoalkanes (RX) obtained using tetramethylsilane as reagent gas show two major peaks corresponding to the cluster ion RX+SiMe3 and alkyl ion R+. Iodides exhibit the highest affinity toward the trimethylsilyl ion and produce the most stable silylated molecular