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Chemical ionization mass spectrometry of halogenoalkanes with tetramethylsilane as reagent gas

โœ Scribed by Oleg S. Chizhov; Valentin I. Kadentsev; Andrei A. Stomakhin

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
314 KB
Volume
26
Category
Article
ISSN
1076-5174

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โœฆ Synopsis

Chemical ionization mass spectra of halogenoalkanes (RX) obtained using tetramethylsilane as reagent gas show two major peaks corresponding to the cluster ion RX+SiMe3 and alkyl ion R+. Iodides exhibit the highest affinity toward the trimethylsilyl ion and produce the most stable silylated molecular ions, whereas bromides and especially chlorides are less reactive toward Me$+ ions and form less stable [ M + SiMe,] + ions.

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