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Selective reaction of hydroxylamine with chromophore during the photocycle of pharaonis phoborhodopsin

โœ Scribed by Masayuki Iwamoto; Yuki Sudo; Kazumi Shimono; Naoki Kamo


Book ID
117047888
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
237 KB
Volume
1514
Category
Article
ISSN
0005-2736

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Various nitrlle oxides were reacted with iron complexed trienes of type 1. The reaction proceeded with good yield and diastereoselectivity (ea. 90/l 0) to give A2-isoxazolines which structures were determined by X-Ray and lH-NMR spectroscopy. A2-isoxazolines, obtained by [3+2] dipolar cycloaddition