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Face selectivity during the cycloaddition reaction of nitrile oxides with iron complexed trienes

✍ Scribed by Thierry Le Gall; Jean-Paul Lellouche; Loïc Toupet; Jean-Pierre Beaucourt

Book ID: 104240333
Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 223 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)89010-9

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✦ Synopsis

Various nitrlle oxides were reacted with iron complexed trienes of type 1. The reaction proceeded with good yield and diastereoselectivity (ea. 90/l 0) to give A2-isoxazolines which structures were determined by X-Ray and lH-NMR spectroscopy. A2-isoxazolines, obtained by [3+2] dipolar cycloaddition of nitrile oxides with olelins,

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