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Selective Oxidation of Sulfides to Sulfoxides with Poly[4-hydroxy(tosyloxy)iodo]styrene.

✍ Scribed by Ping Liu; Shi-juan Liu; Ji-Zhen Zhang; Guan-rong Tian


Publisher
John Wiley and Sons
Year
2006
Weight
15 KB
Volume
37
Category
Article
ISSN
0931-7597

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TMSCl-promoted selective oxidation of su
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Selective oxidation of sulfides to sulfoxides is achieved using H 2 O 2 and TMSCl as the promotor. Aromatic and aliphatic sulfides are oxidized to sulfoxides in excellent yields and in short reaction times. Different functional groups including ketone, alkene, ester, and alcohol are tolerated.