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Selective oxidation of saturated hydrocarbons using an electrochemical modification of the gif system.

✍ Scribed by Gilbert Balavoine; Derek H.R. Barton; Jean Boivin; Aurore Gref; Nubar Ozbalik; Henriette Rivière

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
198 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Gif system for selective hydrocarbon oxidation can be carried out replacing the zinc by a cathodic electrochemical reduction: the yields obtained and the selectivities observed are very similar.

📜 SIMILAR VOLUMES

The selective functionalization of satur
The selective functionalization of saturated hydrocarbons. Part 43. Modified Gif oxidation in acetonitrile
✍ Derek H.R. Barton; Tingsheng Li 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 406 KB

The role ofpyridine and of many substituted pyridines in Gif oxidation chemistry has been examined. In the presence of a suitable pyddine type base most of the solvent can be replaced by acetonitrile without diminishing the yield of oxidation products. The use of 4-tert-butylpyridine permits the iso

The selective functionalization of satur
The selective functionalization of saturated hydrocarbons. Part 36. Stereoselectivity studies of Gif-type reactions
✍ Derek H.R. Barton; Warinthorn Chavasiri 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 352 KB

The stereoselectivity of various Gif-type reactions was evaluated using trans-l,4-dimethylcyclohexane as a chemical probe. The results revealed that these reactions were moderately stereoselective. The outcome of the reactions was preferentially formed in the more stable equatorial configuration.