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Selective oxidation of propylene by O2with visible light in a zeolite

โœ Scribed by Fritz Blatter; Hai Sun; Heinz Frei

Book ID
112412734
Publisher
Springer US
Year
1995
Tongue
English
Weight
688 KB
Volume
35
Category
Article
ISSN
1011-372X

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Highly Selective Formation of tert-Butyl
Highly Selective Formation of tert-Butyl Hydroperoxide from the Reaction of Isobutane and O2 in a Zeolite under Visible Light
โœ Dr. Fritz Blatter; Dr. Hai Sun; Dr. Heinz Frei ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 503 KB

Isobutane and oxygen gas loaded into zeolite BaY react upon irradiation with green or blue light to yield tert-butyl hydroperoxide in a single-photon process. This was discovered when monitoring the reaction at room temperature in situ by FT-infrared spectroscopy. Selectivity was 98%, even upon conv