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Cyclohexanone from Cyclohexane and O 2 in a Zeolite under Visible Light with Complete Selectivity

โœ Scribed by Sun, Hai; Blatter, Fritz; Frei, Heinz


Book ID
118271712
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
243 KB
Volume
118
Category
Article
ISSN
0002-7863

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Highly Selective Formation of tert-Butyl
โœ Dr. Fritz Blatter; Dr. Hai Sun; Dr. Heinz Frei ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 503 KB

Isobutane and oxygen gas loaded into zeolite BaY react upon irradiation with green or blue light to yield tert-butyl hydroperoxide in a single-photon process. This was discovered when monitoring the reaction at room temperature in situ by FT-infrared spectroscopy. Selectivity was 98%, even upon conv