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Selective Oxidation of 1-Butene over Silica-Supported Cr(VI), Mo(VI), and W(VI) Oxides

✍ Scribed by Narayanan C. Ramani; David L. Sullivan; John G. Ekerdt; Jih-Mirn Jehng; Israel E. Wachs


Book ID
112255306
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
297 KB
Volume
176
Category
Article
ISSN
0021-9517

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Oxidation of N,N-benzylalkylamines to ni
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Oxidation of N,N-benzylalkylamines in chloroform by Mo(VI) and W(VI) polyperoxo complexes (PPC) of general formula Q~{P0,[M0(02)2],}'-(Q'= onium ion) yield the corresponding nitrones as oxidized products quantitatively. Only in the case of N,N-benzylmethylamine the formation of nitrone is accompanie