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Selective one-pot synthesis of secondary and tertiary amines via rhodium catalysed reduction and multiple alkylation of aromatic nitro compounds under hydroformylation conditions

✍ Scribed by Thorsten Rische; Peter Eilbracht

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 521 KB
Volume: 54
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)00428-1

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✦ Synopsis

Secondary and tertiary amines are selectively prepared in high yields by a one-pot reduction / multiple alkylation procedure from aromatic nitro compounds with styrenes, cyclic olefins or heterofunctionalised olefins, carbon monoxide and hydrogen in the presence of [Rh(cod)CIL as catalyst.

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