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One-pot synthesis of 1,4-diamines from allyl halides and amines via a rhodium-catalysed multistep reaction sequence under hydroformylation conditions

โœ Scribed by Thorsten Rische; Peter Eilbracht


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
303 KB
Volume
55
Category
Article
ISSN
0040-4020

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Selective one-pot synthesis of secondary
โœ Thorsten Rische; Peter Eilbracht ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 521 KB

Secondary and tertiary amines are selectively prepared in high yields by a one-pot reduction / multiple alkylation procedure from aromatic nitro compounds with styrenes, cyclic olefins or heterofunctionalised olefins, carbon monoxide and hydrogen in the presence of [Rh(cod)CIL as catalyst.