The binuclear MnlV-Mn Iv manganese complex lcatalyzes the periodic acid oxidation of sulfides to sulfones under mild conditions. The reaction was found to be highly selective giving almost quantitative yields of the sulfones even in the presence other easily oxidized groups. Only amines were found t
Selective manganese(III) and vanadium(IV) catalysts for the oxidation of dialkyl sulfides in microemulsion media
β Scribed by Robert W. Hay; Thomas Clifford; Norman Govan
- Book ID
- 110244667
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 175 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0340-4285
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract The kinetics of a net twoβelectron transfer between an authentic Mn^IV^ complex, [Mn(bigH)~3~]^4+^ (__Fig.β 1__; bigHβ=βbiguanideβ=βC~2~N~5~H~7~), and nitrite in aqueous solution in the pH interval 2.00β3.60 is described. Stoichiometric data for the reaction clearly indicates Ξ[Mn^IV^]/Ξ