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Selective insertion of cyclopropylidenes in the formation of bicyclobutanes

โœ Scribed by R.B. Reinarz; G.J. Fonken


Book ID
104238431
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
216 KB
Volume
14
Category
Article
ISSN
0040-4039

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Selective insertion in the formation of
โœ William R. Moore; John B. Hill ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

While the reaction of the dibromocarbene adduct of trimethylethylene with methyllithium gives only trimethylallene, the dibromocarbene adduct of tetramethylethylene reacts with methyllithium to give a nearly quantitative yield of 1,2,2-trimethylbicyclobutane.' We have examined a number of other syst