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Formation of 1-cyclopropylidene-2-phenylethylene in the reaction of ethinylcyclopropane with benzyne

✍ Scribed by Varda Usieli; Shalom Sarel

Book ID
104246870
Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
106 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis

We have lately shown that benzyne is capable of reacting with substituted vinylcyclopropanes

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In previous studies on the stereochemistry of benzyne addition to enol ethers and acetates we observed both stereoselective 2+2 cycloaddition and ene reaction. 1 In each series, however, we found that the proportion of ene product relative to cycloaddition was significantly larger with the trans-is