polar additions or substitutions [71 induced us t o test the wider use of organotin deuterides for deuteration. Using powerful catalysts such as Raney nickel, palladium, platinum [El, or anhydrous ZnClz (91, we obtained both Cdeuterated and C,U-bisdeuterated alcohols smoothly from organotin deuteri
Selective Hydrogenations of 1,1-Disubstituted Cyclopropanes
✍ Scribed by Dipl.-Chem. Claus Gröger; Prof. Dr. Hans Musso
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 259 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Ab initio calculations on the initial steps of the and CH 3 q (q = +, 0, -). Transition structures and energy barriers are obtained for all species, allowing discussion of polymerization process of 1,1-dicyano-, -difluoro-and -dimethyl-substituted cyclopropanes are presented. Polyme-the reaction mec
## Abstract **A breakthrough** in the asymmetric hydroboration of notoriously difficult 1,1‐disubstituted alkenes using a new family of highly effective hydroboration reagents is described (see scheme). The intermediate boranes can be oxidized to alcohols or used in Suzuki–Miyaura cross‐coupling re