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Selective Formation of One or Two C−C Bonds Promoted by Carbanion Addition to [Fe 2 (cp) 2 (CO) 2 (μ-CO)(μ-CSMe)] +

✍ Scribed by Bordoni, Silvia; Busetto, Luigi; Camiletti, Chiara; Zanotti, Valerio; Albano, Vincenzo G.; Monari, Magda; Prestopino, Fabio

Book ID
126273556
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
341 KB
Volume
16
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

Regioselective Addition of tert -BuN⋮C t
Regioselective Addition of tert -BuN⋮C to the α Carbon Atom of the Allenyl Ligand in [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 2α,β -(H)C α C β C γ H 2 }]: Formation of [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 1 -( tert -BuN⋮C)CCCH 3 }] and [Fe 2 (CO) 6 (μ-PPh 2 )(μ-η 1 :η 2 -{ tert -BuNHC(O)CH 2 }CCH 2 )] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 1 -( tert -BuNC)HCCCH 2 }]
✍ Doherty, Simon; Hogarth, Graeme; Waugh, Mark; Scanlan, Tom H.; Clegg, William; E 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 138 KB