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Regioselective Addition of tert -BuN⋮C to the α Carbon Atom of the Allenyl Ligand in [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 2α,β -(H)C α C β C γ H 2 }]: Formation of [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 1 -( tert -BuN⋮C)CCCH 3 }] and [Fe 2 (CO) 6 (μ-PPh 2 )(μ-η 1 :η 2 -{ tert -BuNHC(O)CH 2 }CCH 2 )] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 1 -( tert -BuNC)HCCCH 2 }]

✍ Scribed by Doherty, Simon; Hogarth, Graeme; Waugh, Mark; Scanlan, Tom H.; Clegg, William; Elsegood, Mark R. J.

Book ID
126459301
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
138 KB
Volume
18
Category
Article
ISSN
0276-7333

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