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Selective Electrochemical Retro-Cycloaddition Reaction of Pyrrolidinofullerenes

✍ Scribed by Olena Lukoyanova; Claudia M. Cardona; Margarita Altable; Salvatore Filippone; Ángel Martín Domenech; Nazario Martín; Luis Echegoyen

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
156 KB
Volume
45
Category
Article
ISSN
0044-8249

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Selective Electrochemical Retro-Cycloadd
Selective Electrochemical Retro-Cycloaddition Reaction of Pyrrolidinofullerenes
✍ Olena Lukoyanova; Claudia M. Cardona; Margarita Altable; Salvatore Filippone; Án 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB 👁 1 views

Since the discovery of fullerenes, various methods for their functionalization have been developed and explored extensively. [1] Among the most widely employed derivatization reactions are Diels-Alder cycloadditions, [2] cyclopropanations, [3] and azomethine 1,3-dipolar cycloaddition reactions. [4]

Cover Picture: Retro-Cycloaddition React
Cover Picture: Retro-Cycloaddition Reaction of Pyrrolidinofullerenes (Angew. Chem. Int. Ed. 1/2006)
✍ Nazario Martín; Margarita Altable; Salvatore Filippone; Angel Martín-Domenech; L 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 176 KB 👁 2 views

**Retro‐cycloaddition** of easily prepared pyrrolidinofullerenes affords quantitatively pristine fullerenes, and thus can be used as a new protection‐deprotection protocol in the chemistry of fullerenes, as shown in the cover picture. In their Communication on page 110 ff., N. Martín, L. Echegoyen,