𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Cover Picture: Retro-Cycloaddition Reaction of Pyrrolidinofullerenes (Angew. Chem. Int. Ed. 1/2006)

✍ Scribed by Nazario Martín; Margarita Altable; Salvatore Filippone; Angel Martín-Domenech; Luis Echegoyen; Claudia M. Cardona


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
176 KB
Volume
45
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis


Retro‐cycloaddition of easily prepared pyrrolidinofullerenes affords quantitatively pristine fullerenes, and thus can be used as a new protection‐deprotection protocol in the chemistry of fullerenes, as shown in the cover picture. In their Communication on page 110 ff., N. Martín, L. Echegoyen, and co‐workers report on this promising finding, which has already allowed the selective isolation of the I~h~ constitutional isomer of Sc~3~N@C~80~.


📜 SIMILAR VOLUMES


Cover Picture: Asymmetric Organocatalyti
✍ Tommaso Marcelli; Richard N. S. van der Haas; Jan H. van Maarseveen; Henk Hiemst 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 1 views

**Alkaloids** extracted from the Quinine tree bark are a privileged scaffold for the development of asymmetric organocatalysts. In their Communication on page 929 ff., H. Hiemstra and co‐workers describe a novel __Cinchona__‐derived thiourea compound able to catalyze the Henry (nitroaldol) reaction

Cover Picture: Chiral Borromeates (Angew
✍ Cari D. Pentecost; Andrea J. Peters; Kelly S. Chichak; Gareth W. V. Cave; Stuart 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 143 KB

**Chirality is transferred** from 12 stereogenic centers, all of the same chirality, to the six templating zinc(II) ions in each enantiomer of an optically active Borromeate. Recognizing that the three‐component Borromean link is topologically achiral, J. F. Stoddart et al. describe in their Communi