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Selective Deuteration of Enamines with Deuterated Formic Acids

✍ Scribed by Dr. Walter Himmele; Dr. Wolfgang Bremser; Dr. Hardo Siegel


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
234 KB
Volume
18
Category
Article
ISSN
0044-8249

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## Abstract A number of selectively deuterated derivatives of the common ligand N,N′‐ethylenebis(salicylidenimine), salen, have been prepared. The synthesis involves preparation of selectively deuterated salicylaldehydes. Procedures necessary to carry out these syntheses are described below.

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The Fourier transform infrared spectrum of the n 5 band of deuterated formic acid (DCOOH) has been measured with a resolution of 0.004 cm 01 in the frequency range of 1090-1180 cm 01 . Using a Watson's A-reduced Hamiltonian in the I r representation, a total of 1731 assigned unperturbed transitions

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## Abstract The course of transcarboxylation reactions of potassium salts of deuterated benzenecarboxylic acids was investigated. During the reaction rapid random exchange of hydrogen atoms of the benzene ring for deuterium takes place. The probable mechanism of this exchange, which involves the li