Preparation of selectively deuterated salen ligands
β Scribed by Dennis G. Brown; Chit Srivanavit
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- French
- Weight
- 206 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-2135
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β¦ Synopsis
Abstract
A number of selectively deuterated derivatives of the common ligand N,Nβ²βethylenebis(salicylidenimine), salen, have been prepared. The synthesis involves preparation of selectively deuterated salicylaldehydes. Procedures necessary to carry out these syntheses are described below.
π SIMILAR VOLUMES
## Abstract Three different selectively deuterated propylene oxides have been synthesized for use in quasiβelastic neutron scattering studies of the dynamics of propylene oxide within clathrate hydrate cages. Copyright Β© 2011 John Wiley & Sons, Ltd.
Condensation of the O-protected planar chiral hydroxyferrocene carbaldehyde (S p )-1 with ethylenediamine, followed by deprotection gave rise to the "ferro-salen" ligand (S p ,S p )-3 in good yield.