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Selective deprotection of either alkyl or aryl silyl ethers from aryl, alkyl bis-silyl ethers

✍ Scribed by Sudha V. Ankala; Gabriel Fenteany

Book ID: 104251360
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 120 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00942-5

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✦ Synopsis

A pair of complementary methods was developed using CeCl 3 •7H 2 O/CH 3 CN and LiOH/DMF to selectively deprotect alkyl and aryl silyl ethers, respectively, from the corresponding bis-silyl ethers in excellent yields.

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