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Selective cyclobutane adduct formation in competition with Diels-Alder addition in cation radical cycloadditions

✍ Scribed by Pabon, Raul A.; Bellville, Dennis J.; Bauld, Nathan L.


Book ID
127137705
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
290 KB
Volume
106
Category
Article
ISSN
0002-7863

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Cycloadditions of Allyl Cations, 281)Nov
✍ Hoffmann, H. M. R. ;Vathke-Ernst, Heidrun πŸ“‚ Article πŸ“… 1981 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 457 KB πŸ‘ 1 views

4Methyl-3-penten-2-01 (1) and cyclopentadiene react in an acidic two phase system at 0Β°C to form allylcyclopentenols 2 and norbornenylcarbinols 4. At 50Β°C and under similar conditions, 2 as well as 4 are equilibrated to allylcyclopentadienes 3, bicyclic olefins 5 and 6 , and tricyclic ether 7. With