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Selective colorimetric determination of p-haloaniline in a mixture witho-haloaniline by the reaction with chloranil

✍ Scribed by Hidetaka Yuki; Sachi Matsuda; Yōko Tokuda; Kiyoshi Takiura


Book ID
105127500
Publisher
Springer
Year
1972
Tongue
English
Weight
135 KB
Volume
60
Category
Article
ISSN
0026-3672

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A kinetic spectrophotometric investigation of the reaction of the hydrogen peroxide anion with methyl p-nitrophenyl sulfate in methanol solvent resulted in the evaluation of the pKa of HOOH in methanol at 25'C as 15.8 f 0.2. Since normal kinetic procedures for the determination of the equilibrium co