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Selective cleavage of ketals and acetals

✍ Scribed by Andrew W. Lloyd


Book ID
113411069
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
98 KB
Volume
1
Category
Article
ISSN
1359-6446

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A mild and efficient method for selectiv
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A mild and efficient neutral aqueous method for selective cleavage of acetals and ketals to the corresponding carbonyl compounds has been established by using LiCI in H20-DMSO at elevated temperature. While aryl and ~,~-unsaturated ketals and acetals underwent smooth cleavage, diaryl, non-aryl and i