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Efficient and selective cleavage of acetals and ketals using ferric chloride adsorbed on silica gel

✍ Scribed by Kim, Kwan Soo; Song, Yang Heon; Lee, Bong Ho; Hahn, Chi Sun


Book ID
126053901
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
517 KB
Volume
51
Category
Article
ISSN
0022-3263

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A mild and efficient method for selectiv
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A mild and efficient neutral aqueous method for selective cleavage of acetals and ketals to the corresponding carbonyl compounds has been established by using LiCI in H20-DMSO at elevated temperature. While aryl and ~,~-unsaturated ketals and acetals underwent smooth cleavage, diaryl, non-aryl and i