Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization
✍ Scribed by Nicklas Selander; Benjamin Willy; Kálmán J. Szabó
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 255 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
## Abstract The C—H borylation of simple alkenes catalyzed by a palladium pincer complex is performed in the presence of hypervalent iodine and bis(pinacolato)diboron.
## Abstract Electronically activated alkenes, nonelectronically activated, sterically less demanding alkenes as well as cyclooctene are selectively diborylated under catalysis of palladium complexes (Ia) or (Ib).
Scheme 1. Selective examples of isolated natural products containing chlorinated piperidine moieties. Scheme 2. Pd-catalyzed intramolecular aminohalogenation of alkenes.