✦ LIBER ✦

Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+

✍ Scribed by Bodner, Gerardo S.; Fernandez, Jesus M.; Arif, Atta M.; Gladysz, J. A.

Book ID: 126446112
Publisher: American Chemical Society
Year: 1988
Tongue: English
Weight: 1006 KB
Volume: 110
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00220a082

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Thermodynamic Enantioface-Binding Select

Thermodynamic Enantioface-Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition -Metal Lewis Acid; equilibration of diastereoisomeric (cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium complexes ([Re(η5–C5H5)(CH2 = CHR)(NO) (PPh3)]+BF)

✍ Tang-Sheng Peng; Atta M. Arif; John A. Gladysz 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 German ⚖ 1015 KB

Reactions of monosubstituted alkenes RCH=CH, and [Re(q5-C,H5)(CH2CI,)(NO)(PPh3)]+BF; give complexes ([Re(q5-C5Hs)(CH2=CHR)(NO)(PPh,)l+BF; (la-g) in 63-99 %I yields as mixtures of (RS,SR)-and (RR,SS)-diastereoisomers ( l a (R

Conjugate Additions of Organocuprates to

Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+. Enantioselective Syntheses of 3-Substituted Cycloalkanones

✍ Wang, Yan; Gladysz, J. A. 📂 Article 📅 1995 🏛 American Chemical Society 🌐 English ⚖ 877 KB

Synthesis and reactivity of chiral metal

Synthesis and reactivity of chiral metal fluoride and water complexes derived from the rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+

✍ Agbossou, Sename K.; Roger, Christophe; Igau, Alain; Gladysz, J. A. 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 842 KB

Thermodynamic Aldehyde Enantioface Bindi

Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes [(η5-C5H5)Re(NO)(PPh3)(η2-OCHAr)]BF4

✍ Mr. N. Quirós Méndez; Dr. Charles L. Mayne; Prof. J. A. Gladysz 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 272 KB 👁 1 views

Syntheses of cyclic imine complexes of t

Syntheses of cyclic imine complexes of the chiral rhenium Lewis acid [(ν5-C5H5) Re(NO)(PPh3)]+ by hydride ion abstraction from amido complexes

✍ William R. Cantrell Jr.; George B. Richter-Addo; J.A. Gladysz 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 1020 KB

A New Family of Chiral Chelating Diamine

A New Family of Chiral Chelating Diamines with Transition-Metal Stereocenters: Synthesis, Structure, and Reactivity of the Enantiomerically Pure Dirhenium-Substituted 1,2-Diamine (η 5 -C 5 H 5 )Re(NO)- (PPh 3 )(CH 2 N(CH 3 )CH 2 CH 2 (H 3 C)NCH 2 )(Ph 3 P)(ON)Re(η 5 -C 5 H 5 )

✍ Alvey, Luke J.; Delacroix, Olivier; Wallner, Carsten; Meyer, Oliver; Hampel, Fra 📂 Article 📅 2001 🏛 American Chemical Society 🌐 English ⚖ 249 KB