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Selective benzylation of methyl 2-O-benzyl-α-L-fucopyranoside and benzyl 2,6-di-O-benzyl-β-D-galactopyranoside

✍ Scribed by Surjit S. Rana; Conrad F. Piskorz; Joseph J. Barlow; Khushi L. Matta


Book ID
108308734
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
342 KB
Volume
83
Category
Article
ISSN
0008-6215

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✍ Conrad F. Piskorz; Saeed A. Abbas; Khushi L. Matta 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 428 KB

Condensation of benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-a-D-galactopyranoside with 2,3,4-tri-o-acetyl-a-D-fucopyranosyl bromide in 1: 1 nitromethane-benzene, in the presence of powdered mercuric cyanide, afforded benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-0-(2,3,4-tri-O-acetyl-P-D-fucopyran