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Selective Aromatic Electrochemical Fluorination of Methyl Phenyl Sulfone.

✍ Scribed by B. A. Shainyan; Yu. S. Danilevich; V. K. Bel'skii; A. I. Stash; A. A. Grigor'eva; Yu. A. Chuvashev

Publisher
John Wiley and Sons
Year
2003
Weight
92 KB
Volume
34
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Electrochemical fluorination of aromatic
Electrochemical fluorination of aromatic compounds in liquid R4NF Β· mHFβ€”Part IV. fluorination of chlorobenzene
✍ Kunitaka Momota; Hirohide Horio; Katsuya Kato; Masayuki Morita; Yoshiharu Matsud πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 685 KB

Electrochemical fluorination of chlorobenzene (1) in neat Et,NF mHF (Et = C,H, : m = 4.0, 4.45 and 4.7) was carried out on a platinum anode at 2.3 or 2.5 V vs. Ag/Ag' (0.01 M; M = mol dme3). As the primary products, I-chloro-2-fluorobenzene (2) and 1-chloro-4-fluorobenzene (3) were obtained, whose