Electrochemical Fluorination of Aromatic Compounds in Anhydrous HF.
β Scribed by B. A. Shainyan; Yu. S. Danilevich
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 16 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Electrochemical fluorination of chlorobenzene (1) in neat Et,NF mHF (Et = C,H, : m = 4.0, 4.45 and 4.7) was carried out on a platinum anode at 2.3 or 2.5 V vs. Ag/Ag' (0.01 M; M = mol dme3). As the primary products, I-chloro-2-fluorobenzene (2) and 1-chloro-4-fluorobenzene (3) were obtained, whose
A series of new electrolytes, R,NF.mHF (R: CH,, C,H, and n-C,H,, m > 34, has been utilized for electrochemical fluorination of organic compounds. These electrolytes are non-viscous liquids at room temperature, and have high electrolytic conductivity and high electrochemical stability. The electrolys