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Selective allylation of carbonyl compounds in aqueous media

✍ Scribed by Cathy Einhorn; Jean-Louis Luche

Book ID
103221718
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
495 KB
Volume
322
Category
Article
ISSN
0022-328X

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## Abstract A new and effective Barbier‐Grignard allylation of aldehydes or ketones has been carried out with nano‐aluminum powder in aqueous 0.1 molΒ·L^βˆ’1^ NH~4~Cl (aq.) under an atmosphere of nitrogen. Aromatic carbonyl compounds gave homoallylic alcohols in good yields. The effectiveness of react