Allylation Reactions of Carbonyl Compounds Using an Organosilicon Reagent in Aqueous Media.
β Scribed by Naohiro Aoyama; Tomoaki Hamada; Kei Manabe; Shu Kobayashi
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 107 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A new and effective BarbierβGrignard allylation of aldehydes or ketones has been carried out with nanoβaluminum powder in aqueous 0.1 molΒ·L^β1^ NH~4~Cl (aq.) under an atmosphere of nitrogen. Aromatic carbonyl compounds gave homoallylic alcohols in good yields. The effectiveness of react
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