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ChemInform Abstract: Scandium Trifluoromethanesulfonate Catalyzed Chemoselective Allylation Reactions of Carbonyl Compounds with Tetraallylgermane in Aqueous Media.

✍ Scribed by Takahiko Akiyama; Junko Iwai; Megumi Sugano

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

reactions of organo-metal compounds reactions of organo-metal compounds O 0350 38 -084 Scandium Trifluoromethanesulfonate Catalyzed Chemoselective Allylation Reactions of Carbonyl Compounds with Tetraallylgermane in Aqueous Media.

-The Sc(O-Tf) 3 -catalyzed chemoselective allylation of carbonyl compounds (I) and (IV) with tetraallylgermane is investigated. In most cases, the presence of water is indispensable for the achievement of high yields.

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