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Selective Alkylations of Certain Phenolic and Enolic Functions with Lithium Carbonate/Alkyl Halide

✍ Scribed by Wymann, Walter; Davis, Roman; Patterson, John; Pfister, Jürg

Book ID
119998128
Publisher
Taylor and Francis Group
Year
1988
Tongue
English
Weight
210 KB
Volume
18
Category
Article
ISSN
0039-7911

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✍ Mariko Goto; Koh-ichi Akimoto; Kazumasa Aoki; Mitsuru Shindo; Kenji Koga 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 241 KB

The rate of the reaction of the lithium enolate of 1-tetralone with alkyl halides was enhanced greatly in the presence of 3 equivalents of 1,1,4,7,10,10-hexamethyltriethylenetetramine. The ratio of the monoalkylated product to the dialkylated product was found to have increased under a shorter react