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Selective Alkylation of Amines with Alcohols by Cp*–Iridium(III) Half-Sandwich Complexes

✍ Scribed by Wetzel, Alexander; Wöckel, Simone; Schelwies, Mathias; Brinks, Marion K.; Rominger, Frank; Hofmann, Peter; Limbach, Michael

Book ID
120520573
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
551 KB
Volume
15
Category
Article
ISSN
1523-7060

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N-Alkylation of amines with alcohols cat
N-Alkylation of amines with alcohols catalyzed by a Cp*Ir complex
✍ Ken-ichi Fujita; Zhenzi Li; Naohiro Ozeki; Ryohei Yamaguchi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 493 KB

A new effective catalytic system consisting of [Cp\*IrCl 2 ] 2 /K 2 CO 3 (Cp\*=pentamethylcyclopentadienyl) for the N-alkylation of primary amines with alcohols has been developed. As an example, the reaction of aniline with benzyl alcohol in the presence of [Cp\*IrCl 2 ] 2 (5.0 mol%Ir) and K 2 CO 3