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Reactions of Cp*Ir(CO)2 with pentafluorobenzonitrile: Half-sandwich iridium complexes Cp*Ir(CO)(p-C6F4CN)(X)

✍ Scribed by Mak, Kar Hang Garvin; Chan, Pek Ke; Fan, Wai Yip; Leong, Weng Kee; Li, Yongxin


Book ID
122787087
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
713 KB
Volume
741-742
Category
Article
ISSN
0022-328X

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Half-sandwich complexes ,/ Iridium complexes ,/ cyclo-Sulfido ligands / cyclo-Selenido ligands / Iridacycles ~~ ~~ Cp\*Ir(PMe3)C12 (1) reacts with chalcogenide ligand sources such as (NH4)& (x x lo), (NEt&Se6, and H,Se to yield the half-sandwich complexes Cp\*Ir(PMe,)(S,) In = 4 (2a), 6 (4a)l and Cp

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