Selection of a solvent for adductive crystallization
β Scribed by J.P. Tare; M.R. Chivate
- Book ID
- 103002756
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 536 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-2509
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β¦ Synopsis
Abshct-A procedure for screening solvents for adductive crystallization by use of the data on the enthalpy changes on complex formation, which can be easily measured experimentally, is proposed. Two parameters chemical theory of Harris and Prausnitz has been utilized for calculations of activity coefficients and selectivity values. This method of screening solvents for adductive crystallization seems to be useful for practical applications.
π SIMILAR VOLUMES
A correlation involving solubility parameters to predict the selectivity of a solvent for extractive crystallisation has been developed. It has been found that predicted and observed values of selectivity agree well for extractive crystallisation processes. However, in case of adductive crystallisat