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Seeing the Long-Sought Intermediate in the Reaction of Oxoiron(IV) Porphyrin Cation Radicals with Olefins

✍ Scribed by Gross, Zeev; Nimri, Shay


Book ID
126227499
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
303 KB
Volume
117
Category
Article
ISSN
0002-7863

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## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford