Seeded emulsion polymerization of styrene: influence of acrylic acid on the particle growth process

✍ Scribed by M. Slawinski; M. A. J. Schellekens; J. Meuldijk; A. M. Van Herk; A. L. German

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 161 KB
• Volume: 76
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/(sici)1097-4628(20000516)76:7<1186::aid-app22>3.0.co;2-n

✦ Synopsis

The seeded batch emulsion copolymerization of styrene and acrylic acid was studied. The polymerization rate was investigated with pH as the main parameter. Some attempts were made to evaluate the average number of growing chains per particle during Stage II of the emulsion polymerization process. The final latex products were characterized by means of conductometric aqueous titration and potentiometric titration in an organic solvent mixture. The distribution of the acid groups over the aqueous phase, the particle surface, and the interior of the particles together with the kinetic results provided insight into important features governing the incorporation of acrylic acid. The results indicate that pH is the dominating parameter for the incorporation process. An optimal incorporation on the surface of the particles is observed for a low value of pH. In that case, all the acid groups are protonated.