A relation between the dynamic electrophoretic mobility of spherical colloidal particles in a concentrated suspension and the colloid vibration potential (CVP) generated in the suspension by a sound wave is obtained from the analogy with the corresponding Onsager relation between electrophoretic mob
Sedimentation Potential in a Concentrated Suspension of Spherical Colloidal Particles
โ Scribed by Hiroyuki Ohshima
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 199 KB
- Volume
- 208
- Category
- Article
- ISSN
- 0021-9797
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โฆ Synopsis
A theory of sedimentation in a concentrated suspension of spherical colloidal particles proposed by Levine et al. (J. Colloid Interface Sci. 57, 424 (1976)) is further developed to derive a simple convenient expression for the sedimentation potential applicable for low zeta potentials and nonoverlapping electrical double layers of adjacent particles. An Onsager relation between the sedimentation potential and electrophoretic mobility of spherical colloidal particles in concentrated suspensions is derived.
๐ SIMILAR VOLUMES
A general expression for the electrical conductivity of a concentrated suspension of spherical colloidal particles is obtained for the case where the particle zeta potential is low and the overlapping of the electrical double layers of adjacent particles is negligible by using Kuwabara's cell model.
A theory of sedimentation in a concentrated suspension of spherical soft particles (i.e., polyelectrolyte-coated particles) is developed to obtain general expressions for sedimentation velocity of soft particles and sedimentation potential in the suspension. An Onsager relation between sedimentation
for a swarm of spherical particles applicable for low z poten-A general mobility expression is derived for a swarm of identical tials and all ka values, showing that as ka decreases and/ spherical colloidal particles in concentrated suspensions on the or the particle volume fraction increases (the p
for the dynamic mobility of spherical particles which is ap-A theory for the dynamic electrophoretic mobility m of spherical plicable for all ka (k is the Debye-Hu ยจckel parameter and colloidal particles in concentrated suspensions in an oscillating a is the particle radius) at zero particle permitt
The electrophoretic behavior of concentrated spherical colloidal particles is analyzed theoretically for all levels of scaled surface potential ฯa, taking the effect of double-layer polarization (DLP) into account. The result of numerical simulation reveals that for a very small kappaa (<0.01), kapp